What are glyoxal’s physico-chemical characteristics?

- Chemical properties of glyoxal 40%:
Form: liquid Color: colorless to pale yellow (color index: max. 20 APHA) Odor: almost odorless Solubility: miscible with water and with all water-miscible organic solvents
- Physical properties of glyoxal 40%:
Freezing point: approx. -14°C Boiling point: approx. 104°C Density at 20°C: approx. 1.27 g/cm3 pH: 2 to 3.5 Ignition temp.: 285°C Acid number: 1.5 mg KOH/g max. Formaldehyde: 100 ppm max. Vapor pressure of glyoxal 40% at 20°C: 24 mbar Evaporation of the 40% solution yields a white solid mass of polyglyoxal.
What about glyoxal’s chemical behavior?

As the simplest dialdehyde, glyoxal undergoes reactions characteristic of aldehydes.
Glyoxal is an excellent crosslinking agent for starch, cellulose (e.g. hydroxy ethyl cellulose), proteinaceous material (e.g. gelatine, soy protein), polyacrylamide, and polyvinyl alcohols.
Glyoxal preferably binds to functional groups like hydroxy, amino or amido functionalities.
What are current fields of application for glyoxal?

Glyoxal is a versatile crosslinker for textile, paper, oil/gas, cosmetics and leather applications.
In addition its biocidal activity explains its role in disinfectants.
Glyoxal is also used as a building block in special epoxy resins and for imidazoles.
Glyoxylic acid is manufactured from glyoxal and serves as an intermediate for several applications.
What benefits does BASF offer glyoxal customers?
Glyoxal from BASF provides sustainable solutions that fulfill customer needs. On the strength of our resources we deliver more than the product.

- Delivering glyoxal reliably around the world
BASF’s annual global output of 80,000 metric tons makes the company the No. 1 producer of glyoxal. ”We are there, wherever our customers operate.” Our globe-spanning operations put us within local reach. Reliable supply: glyoxal is part of BASF’s petrochemical value chain.
- BASF’s glyoxal application services make its customers successful faster
With over 55 years of experience in glyoxal R&D and recourse to more than 8,300 in-house R&D practitioners, we are positioned to supply significant glyoxal applications know-how. BASF’s pipeline is filled with new products and applications from the glyoxal value-chain (e.g. imidazole and ionic liquids). BASF’s worldwide technical marketing and joint development with customers yield successful tailor-made solutions. Last but not least, BASF’s proven track record as an innovative partner makes customers more successful.
- Customer-specific logistics services
BASF supplies bulk or packaged materials throughout the world, advises on packaging and, on request, develops tailor-made responses. BASF’s global logistics and sales team services provides efficiencies in expediting shipments, drawing on dedicated storage facilities to ensure supply.
- Sustainable development of customer products made with our glyoxal
BASF will register glyoxal under the “Biocidal Products Directive” as well as REACH. BASF advises on REACH-related issues. BASF successfully completed and submitted the European registration for cosmetic applications and in the United States registered glyoxal with the FDA as a component in food packaging applications. Glyoxal, being a biodegradable product in conformance with OECD criteria, enhances efforts to boost sustainability.
 

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